Artopia Mosaics & Sculpture
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SCULPT & STICK (S&S) SAFETY DATA SHEET
PRODUCT NAME: Sculpt & Stick (S&S)
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name: Sculpt & Stick (S&S)
Relevant identified uses: Sculpture Medium and Tile adhesive.
Contact: Artopia Technical Manager Sebastian Bellino 0408 180 169
Email: [email protected]
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
Hazard This product is hazardous according to the criteria of the ASCC. All Classification components are listed on the AICS. Not classified as Dangerous goods according to the ADG Code. Not a scheduled poison according to SUSDP. Contains crystalline silica, a category 1 carcinogen. Risk Phrase(s) R20 Harmful by inhalation R36/37/38 Irritating to eyes, respiratory system and skin. R41 Risk of serious damage to eyes. R49(1) May cause cancer by inhalation R66 Repeated exposure may cause skin dryness and cracking. Safety Phrase(s) S22 Do not breathe dust S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with [plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S36/37 Wear suitable protective clothing and gloves. S38 If insufficient ventilation, wear suitable respiratory equipment.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Solid Characterisation Information on Name CAS Proportion Composition
Sand 14808-60-7 20-40%
White Portland cement 65997-15-1 30-60%
Non Hazardous Ingredients 30-60%
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
- For acute or short term repeated exposures to iron and its derivatives:
- Always treat symptoms rather than history.
- In general, however, toxic doses exceed 20 mg/kg of ingested material (as elemental iron) with lethal doses exceeding 180 mg/kg.
- Control of iron stores depend on variation in absorption rather than excretion. Absorption occurs through aspiration, ingestion and burned skin.
- Hepatic damage may progress to failure with hypoprothrombinaemia and hypoglycaemia. Hepatorenal syndrome may occur.
- Iron intoxication may also result in decreased cardiac output and increased cardiac pooling which subsequently produces hypotension.
- Serum iron should be analysed in symptomatic patients. Serum iron levels (2-4 hrs post-ingestion) greater that 100 ug/dL indicate poisoning with levels, in excess of 350 ug/dL, being potentially serious. Emesis or lavage (for obtunded patients with no gag reflex)are the usual means of decontamination.
- Activated charcoal does not effectively bind iron.
- Catharsis (using sodium sulfate or magnesium sulfate) may only be used if the patient already has diarrhoea.
- Deferoxamine is a specific chelator of ferric (3+) iron and is currently the antidote of choice. It should be administered parenterally. [Ellenhorn and Barceloux: Medical Toxicology]
- For acute or short term repeated exposures to dichromates and chromates:
- Absorption occurs from the alimentary tract and lungs.
- The kidney excretes about 60% of absorbed chromate within 8 hours of ingestion. Urinary excretion may take up to 14 days.
- Establish airway, breathing and circulation. Assist ventilation.
- Induce emesis with Ipecac Syrup if patient is not convulsing, in coma or obtunded and if the gag reflex is present.
- Otherwise use gastric lavage with endotracheal intubation.
- Fluid balance is critical. Peritoneal dialysis, haemodialysis or exchange transfusion may be effective although available data is limited.
- British Anti-Lewisite, ascorbic acid, folic acid and EDTA are probably not effective.
- There are no antidotes.
- Primary irritation, including chrome ulceration, may be treated with ointments comprising calcium-sodium-EDTA. This, together with the use of frequently renewed dressings, will ensure rapid healing of any ulcer which may develop.
- The mechanism of action involves the reduction of Cr (VI) to Cr(III) and subsequent chelation; the irritant effect of Cr(III)/ protein complexes is thus avoided. [ILO Encyclopedia]
[Ellenhorn and Barceloux: Medical Toxicology]
- Manifestation of aluminium toxicity include hypercalcaemia, anaemia, Vitamin D refractory osteodystrophy and a progressive encephalopathy (mixed dysarthria-apraxia of speech, asterixis, tremulousness, myoclonus, dementia, focal seizures). Bone pain, pathological fractures and proximal myopathy can occur.
- Symptoms usually develop insidiously over months to years (in chronic renal failure patients) unless dietary aluminium loads are excessive.
- Serum aluminium levels above 60 ug/ml indicate increased absorption. Potential toxicity occurs above 100 ug/ml and clinical symptoms are present when levels exceed 200 ug/ml.
- Deferoxamine has been used to treat dialysis encephalopathy and osteomalacia. CaNa2EDTA is less effective in chelating aluminium.
[Ellenhorn and Barceloux: Medical Toxicology]
- For acute or short-term repeated exposures to highly alkaline materials:
- Respiratory stress is uncommon but present occasionally because of soft tissue edema.
- Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary.
- Oxygen is given as indicated.
- The presence of shock suggests perforation and mandates an intravenous line and fluid administration.
- Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow deep penetration into the tissue.
Alkalis continue to cause damage after exposure.
INGESTION:
- Milk and water are the preferred diluents
(No more than 2 glasses of water should be given to an adult.)
- Neutralising agents should never be given since exothermic heat reaction may compound injury.
* Catharsis and emesis are absolutely contra-indicated.
* Activated charcoal does not absorb alkali.
* Gastric lavage should not be used.
Supportive care involves the following:
- Withhold oral feedings initially.
- If endoscopy confirms transmucosal injury start steroids only within the first 48 hours.
- Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention.
- Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).
SKIN AND EYE:
Injury should be irrigated for 20-30 minutes.
Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
Special hazards arising from the substrate or mixture
Advice for firefighters
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
See section 8
Environmental precautions
See section 12
Methods and material for containment and cleaning up
Personal Protective Equipment advice is contained in Section 8 of the SDS
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL)
INGREDIENT DATA
EMERGENCY LIMITS
Exposure controls
Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:2000 & 149:001, ANSI Z88 or national equivalent)
* - Negative pressure demand ** - Continuous flow
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
SECTION 10 STABILITY AND REACTIVITY
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
SECTION 12 ECOLOGICAL INFORMATION
No data available
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant: NO
HAZCHEM: Not Applicable
Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
Transport in bulk according to Annex II of MARPOL and the IBC code: Not Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
PORTLAND CEMENT (65997-15-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
GRADED SAND (14808-60-7.) IS FOUND ON THE FOLLOWING REGULATORY LISTS
Australia Exposure Standards
Australia Hazardous Substances Information System - Consolidated Lists Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs
SECTION 16 OTHER INFORMATION
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviations
PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limi
t IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
Print Date: 13/10/2017 end of SDS
ARTISTSIC TINTS: INFORMATION AND SAFETY DATA SHEET www.artopiamosaics.com
Thank you for purchasing this product. Artistic Tints are a range of intense liquid colorants for tinting grout, adhesive, paint and other coatings. Artopia stocks 25 Exciting Colours. See website for the full colour range.
DIRECTIONS FOR USE: DO NOT OPEN TUBE BY REVERSING CAP. Instead, pierce with a small pointed instrument to prevent spillage and to ensure the cap is kept clean. You will also need to wash hands and wipe surfaces if even a small amount is spilt, otherwise the colour can easily spread to other surfaces.
Prepare grout or adhesive (or other coating) in the usual manner. Add a small amount of the tint and stir. It is best to add a little at a time with a small stick, otherwise you may end up with a colour much deeper than you intended. You can create pastel shades by adding just a tiny amount of tint. You can increase the intensity of your grout/glue/paint by adding more. Do not add more than 10% tint content to your grout/glue/paint, or you can compromise the integrity of the base product.
Colours can be mixed together to create other colours. Colours can be made lighter or darker by adding white tint or white grout/adhesive.
PRODUCT INFORMATION
Water soluble. UV stable. Be wary that extreme exposure to direct sunlight may cause fading over time.
Keep tubes tightly closed. Store in a dry, cool place. Keep away from direct sunlight and protect from freezing.
WARNING: Artistic Tints are extremely intense and a little bit goes a long way, which means without undue care the colour can spread where you don’t want it. Will stain clothing, furniture and surfaces, so handle with care.
SAFETY INFORMATION
Not classified as Dangerous Goods by criteria of the Australian Dangerous Goods Code for Transport by Road and Rail. This material is non-hazardous according to the criteria of Australian Safety and Compensation Council.
No adverse health effects expected if the product is handled in accordance with guidelines provided. Handle in accordance with good industrial hygiene and safety practices. If mishandled symptoms may arise: skin irritation, eye irritation or damage, irritation to mouth, throat and digestive tract.
SAFETY INFORMATION: Avoid contact with skin and eyes and clothing. Do not ingest or inhale.
EYE CONTACT: In case of danger of splashes of product, wear safety glasses with side shields. Classified as a moderate eye irritant. If used incorrectly and eye contact is made, it may cause tearing, reddening and/or swelling.
SKIN CONTACT: May cause skin irritation. Prolonged or repeated contact may result in defatting and drying of the skin causing irritation and dermatitis (rash). Use protective gloves.
INHALATION & INGESTION: If used incorrectly inhalation may cause lung irritation. If used incorrectly ingestion may cause mild to severe symptoms of poisoning. Use mask.
First Aid Measures:
Inhalation: Provide fresh air, seek medical advice if necessary.
Skin Contact: Wash with plenty of water and seek medical attention if irritation develops. Remove and wash contaminated clothing before re-use.
Eye Contact: Rinse immediately with plenty of water for at least 15 minutes. If symptoms persist, call a physician.
Ingestion: Do not induce vomiting. Clean mouth with water. After doing so, drink plenty of water. If symptoms persist call a physician.
Notes to Physician: Symptomatic treatment.